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Using catalysts is of paramount worth in providing responsible ways of SiO2 ALD. Devoid of catalysts, surface reactions bringing about the formation of SiO2 are normally quite sluggish and only take place at exceptionally higher temperatures. Typical catalysts for SiO2 ALD involve Lewis bases such as NH3 or pyridine and SiO2; ALD can also be initiated when these Lewis bases are coupled with other silicon precursors which include tetraethoxysilane (TEOS).[24] Hydrogen bonding is considered to come about involving the Lewis foundation as well as the SiOH* surface species or concerning the H2O centered reactant along with the Lewis base. Oxygen gets to be a much better nucleophile in the event the Lewis base hydrogen bonds With all the SiOH* surface area species because the SiO-H bond is effectively weakened.
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